Adiabatic potential energy curves of were calculated by means of pseudopotentialmethod. Very good agreement between the calculated and the experimental curvesallowed for a reliable description of the dissociation process through potentialenergy barriers. The barrier supports several rovibrational quasi-bound states andexplicit time evolution of these states via the time-dependent nuclear Schroedingerequation showed that the state populations decay exponentially in time. We wereable to precisely describe the time-dependent dissociation process of severalrovibrational levels and found that our calculated spectrum match very well withthe assigned experimental spectrum. Moreover, our approach is able to predictthe positions of previously unassigned lines, particularly in the case of theirlow intensity.
room B2.38, Pasteura 5 at 10:00

Prof. Rene Gerritsma (Uniwersytet w Amsterdamie)
In recent years, a novel field of physics and chemistry has developedin which trapped ions and ultracold atomic gases are made to interactwith each other. These systems find applications in studying quantumchemistry and collisions [1], and a number of quantum applications areenvisioned such as ultracold buffergas cooling of the trapped ionquantum computer and quantum simulation of fermion-phonon coupling[2]. Up until now, however, the ultracold temperatures required forthese applications have not been reached, because the electric trapsused to hold the ions cause heating during atom-ion collisions [3]. Inour experiment, we overlap a cloud of ultracold 6Li atoms in a dipoletrap with a 171Yb+ ion in a Paul trap. The large mass ratio of thiscombination allows us to suppress trap-induced heating. For the veryfirst time, we buffer gas-cooled a single Yb+ ion to temperaturesclose to the quantum (or s-wave) limit for 6Li-Yb+ collisions. We findsignificant deviations from classical predictions for the temperaturedependence of the spin exchange rates in these collisions. Our resultsopen up the possibility to study trapped atom-ion mixtures in thequantum regime for the first time. Finally, I will present a novel wayto control interactions between atoms and ions, that employsRydberg-coupling of the atoms to tune their polarizability [4,5].[1] M Tomza et al., arXiv:1708.07832 (2017).[2] U. Bissbort et al., Phys. Rev. Lett. 111, 080501 (2013).[3] M. Cetina et al., Phys. Rev. Lett. 109, 253201 (2012).[4] T. Secker et al., Phys. Rev. Lett. 118, 263201 (2017).[5] N. Ewald et al., arXiv:1809.03987 (2018).